Calculating Enthalpy Changes Using Hesss Law

Hesss Law, also known as Hesss Law of Constant Heat Summation, states that the total enthalpy of a chemical reaction is the sum of the enthalpy changes for the steps of the reaction. Therefore, you can find enthalpy change by breaking a reaction into component steps that have known enthalpy values. This example problem demonstrates strategies for  how to use Hesss Law to find the enthalpy change of a reaction using enthalpy data from similar reactions. Hesss Law Enthalpy Change Problem What is the value of ΔH for the following reaction? CS2(l) 3 O2(g) → CO2(g) 2 SO2(g) Given: C(s) O2(g) → CO2(g); ΔHf -393.5 kJ/molS(s) O2(g) → SO2(g); ΔHf -296.8 kJ/molC(s) 2 S(s) → CS2(l); ΔHf 87.9 kJ/mol Solution Hesss Law says the total enthalpy change does not rely on the path taken from beginning to end. Enthalpy can be calculated in one grand step or multiple smaller steps. To solve this type of problem, organize the given chemical reactions where the total effect yields the reaction needed. There are a few rules that you must follow when manipulating a reaction. The reaction can be reversed. This will change the sign of ΔHf.The reaction can be multiplied by a constant. The value of ΔHf must be multiplied by the same constant.Any combination of the first two rules may be used. Finding a correct path is different for each Hesss Law problem and may require some trial and error. A good place to start is to find one of the reactants or products where there is only one mole in the reaction. You need one CO2, and the first reaction has one CO2 on the product side. C(s) O2(g) → CO2(g), ΔHf -393.5 kJ/mol This gives you the CO2 you need on the product side and one of the O2 moles you need on the reactant side. To get two more O2 moles, use the second equation and multiply it by two. Remember to multiply the ΔHf by two as well. 2 S(s) 2 O2(g) → 2 SO2(g), ΔHf 2(-326.8 kJ/mol) Now you have two extra Ss and one extra C molecule on the reactant side that you dont need. The third reaction also has two Ss and one C on the reactant side. Reverse this reaction to bring the molecules to the product side. Remember to change the sign on ΔHf. CS2(l) → C(s) 2 S(s), ΔHf -87.9 kJ/mol When all three reactions are added, the extra two sulfur and one extra carbon atoms are canceled out, leaving the target reaction. All that remains is adding up the values of ΔHf. ΔH -393.5 kJ/mol 2(-296.8 kJ/mol) (-87.9 kJ/mol)ΔH -393.5 kJ/mol - 593.6 kJ/mol - 87.9 kJ/molΔH -1075.0 kJ/mol Answer:  The change in enthalpy for the reaction is -1075.0 kJ/mol. Facts About Hesss Law Hesss Law takes its name from Russian chemist and physician Germain Hess. Hess investigated thermochemistry and published his law of thermochemistry in 1840.To apply Hesss Law, all of the component steps of a chemical reaction need to occur at the same temperature.Hesss Law may be used to calculate  entropy and Gibbs energy in addition to enthalpy.

Short Story Analysis “a Television Drama” - 845 Words

Short Story Analysis: â€Å"A Television Drama† Plot Summary The short story’s plot begins by introducing the main character Carolee Mitchell. Carolee is in her home doing her daily chores when suddenly she looks out her window to find many policeman, police dogs and police cars outside on her street. Carolee did not know what was happening so she continued on with her chores. In a few moments Carolee notices a young man drenched in blood in her garden outside. Carolee wants to call the police but questions what good it would be considering they are already on her street. She wants to call someone but none of her neighbors were home. Thinking that he was injured and maybe was not even the man the police were after, she looked out the window†¦show more content†¦Setting The story takes place in a neighborhood that i estimate is quite small considering Carolee knows her neighbors are gone. The setting revolves around Carolee’s home. Her doing her chores in her home and the suspect roaming around outside. The setting influe nces the story a lot because it influences Carolee’s reaction to what happened. She had never seen anything like that in person and it opened her eyes to how society really is. Conflict In the story there are 3 types of conflict, Person vs. Self, Person vs. Society and Person vs. Person. Person vs. Self would come in when Carolee had to decide what she was gonna do. Would she call the police or help the person or just leave well alone. Person vs. Society would be the police force against the suspect. Finally Person vs. Person would be when the suspect shot the other police officer and when he was getting shot at. St.Croix 3 Symbolism I believe that Carolee symbolises many people in our society at the moment. People who are oblivious to what is actually happening and how our society functions. Her reaction to what happened how the police came into her neighborhood and how the man was drenched in blood and was tumbling around showed lack of experience. Like lack of knowledge of what was actually going on. Literary Devices In the story the author used foreshadowing. The foreshadowing came in when Carolee heard the dogs barking. This foreshadowed that something was found or the dogs found someone soShow MoreRelatedRepresentations Of Religion And Western Media1499 Words   |  6 Pagesjournalists and politicians are ‘segregated’, ‘beaten’, ‘insults’, ‘veil’, ‘freedom’, ‘mistreated’ ‘religion’, ‘hatred’, ‘human rights’, ‘tortured’. 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One Simple Trick for 4th Grade Scholarship Essay Samples Unveiled

One Simple Trick for 4th Grade Scholarship Essay Samples Unveiled Considering all the knowledge areas and tips that you're already conscious of in writing a scholarship letter, it is possible to easily put together all of the information that you must make sure you and your scholarship letter will stick out. As a consequence, their scholarship applications become rejected. You should submit an application for scholarships online. Many students don't keep the coherency in the content. EssayDog can help you determine the elements of a fantastic story that you can then use to create an outstanding essay. Essay samples allow you to acknowledge the manner in which an amazing writer blends theoretical and practical facets. It's highly suggested that you outline an essay at first before finally writing its true content. To increase the odds of your essay being successful, analyze the institution you're applying to. Informative essay writing is an art that each student should master. Don't forget to begin your essay strongit should have the capacity to spark the interests of your readers. You don't need to possess the very best writing skills as a way to be creative and compose an effective essay. You ought to understand the actual intention of why it is you are writing a scholarship essay. It's simple to point out an essay which has been written solely for the interest of it. Without understanding the significance of the vital themes, it is not possible to compose an impeccable essay. To win, you've got to write a brief essay about the Seventh Amendment and the way it influences your life. Likewise, it has to be logically complete and express a particular idea. You like individuals who have a positive standpoint. There's one important thing you should know before even starting to collect material for your scholarship letter. Be certain to leave enough time to compose this part. Scholarship sponsors search for applicants with vision and motivation, so they may ask about your targets and aspirations. Scholarship essays are a critical matter. Being invited for a scholarship application is a remarkable experience that's why you have to make the absolute most out of it. Concentrate on the objective of the scholarship. Students are also requested to compose scholarship essays on several social difficulties. They need to adopt a unique approach to deal with the theme. They need to mention their goals. They need to focus on their strengths. With their aid, you can properly lean when to empathize your abilities and talents on the essay and your achievements. Additional background knowledge provides you with more confidence. Students basically must write the method by which they implement their theoretical knowledge in practical life to be able to attain success. What's Truly Happening with 4th Grade Scholarship Essay Samples The end of the essay should restate the major theme. There are various letter documents and essay examples that are employed in the area of education. A scholarship essay could possibly be intimidating to make in the beginning, particularly if you don't know about the ways on the way you can readily create this document. For example, there isn't any suitable method of drafting a college application essay. The debut of each written work ought to have a very clear thesis statement or argument. Your success will heavily be based on the language and tone you are using in your essay. You will also get to take a look at a couple of essay examples, along with a list of do's and don'ts that is likely to make the writing process even simpler for you. Therefore, students have to be quite careful whilst writing this statement. 4th Grade Scholarship Essay Samples Help! Bear in mind there are some instructions that ask that you use a specific structure or format. All things considered, the content has a fantastic flow, and the entire paper is simple to read. Your collection of words and the way you construct your sentences are some points that could influence your application. It's natural for students not to remember all details and rules of formatting. What You Need to Do About 4th Grade Scholarship Essay Samples Before You Miss Your Chance Most flawless college admission essay exampl es exhibit characteristics which may be noticed in each one of the samples. Your future is dependent on it. The scholarship essay examples shared here are a fantastic plan in telling you the way to compose the ideal scholarship essay. An essay has a specific structure. You'll learn precisely what you want to do in order to create the ideal scholarship essay. The scholarship example essay is significantly needed in giving you the correct format to earn a scholarship essay.

Lost Boy Essay Example For Students

Lost Boy Essay Dave Peltzer the author of The Lost Boy tells his story from the time he left hisabusive mother and alcoholic father, through his experiences in five foster homes andjuvenile detention, and how he eventually made it into the Air Force. He was a defiant,rebellious boy who, despite his background and personality, managed to endear himselfto many guardians, social workers, and teachers. Pelzer writes in an honest, sometimesrambling, style; he is never bitter, and his story will find many sympathetic readers. Themain purpose for Dave to write this book is to show at what lengths children andadolescents have gone to over come the unmentionable hardships of and abusive family. The three most valuable things I have learned from this book are very hard tochoose. The book was full of many things to help me in my everyday life. Ranging fromhow to deal with kids who have be through abusive situations to how kids of abuse act ingeneral. The first one has to be, Dave was very tactful in how he ha ndled his thoughts andfeelings. Many children his age are running around chasing girls and hanging with theguys. Not him he was studying hard and trying to be better than his parents were. Hewould always squander away what he had, so no one could take what was rightfully hisand that includes his life. The second thing that was useful was how Dave was neverangry with his situation he would just look at it as another challenge. Many times throughout the book Dave would have to change foster homes after being fairly settled in theway of living there. Most teens his age cant handle a great deal of change but Davewould just go with the flow and never bat an eye lash. The third most valuable thing hasto be his willingness to help. I would think that since no one would help him he wouldnot help anyone else. On the contrary, Dave was always helping with chores, makingdinner, and doing little extra things he didnt have to do. I later found out through readingthe book that Daves willingness t o help stems from his need to feel loved and wanted. I can honestly say that I could never have gone through the painstaking trials andtribulations Dave went though while he was in his teen yes. It take a special person to dothat and Dave is that special person. PARENTING TECHNIQUESDaves mother was a very troubled woman who for some unknown reason liked totarget Dave and blame him for any and all bad things that happened. His mother was andAuthoritative and neglectful at the same time. Some may say how can one parent be onboth extremes of things but there are a few instance with in the book which shows both. For example Daves mother would make him do all the chores and never was aloud toplay. For some reason even if Dave finished what he was told to do in the time he wastold to do it he would not be fed or worse he would be part of his mother Games andTest. His mothers Games and Tests range from putting him in freezing cold water for5 hours at a time to making him sit on the garage steps with his hands under his bottomhead strait a head for up to 36 hours at a time no food, bathroom, shower or other needs tolive. Dave was saved from this horror when he was 15 but he was in foster care and theparenting techniques ranged from authoritarian to indulgent, but anything was better thanwhat he had endured at his mothers house. .u5cd6aef2be4ac77d9250387a2ad3286e , .u5cd6aef2be4ac77d9250387a2ad3286e .postImageUrl , .u5cd6aef2be4ac77d9250387a2ad3286e .centered-text-area { min-height: 80px; position: relative; } .u5cd6aef2be4ac77d9250387a2ad3286e , .u5cd6aef2be4ac77d9250387a2ad3286e:hover , .u5cd6aef2be4ac77d9250387a2ad3286e:visited , .u5cd6aef2be4ac77d9250387a2ad3286e:active { border:0!important; } .u5cd6aef2be4ac77d9250387a2ad3286e .clearfix:after { content: ""; display: table; clear: both; } .u5cd6aef2be4ac77d9250387a2ad3286e { display: block; transition: background-color 250ms; webkit-transition: background-color 250ms; width: 100%; opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #95A5A6; } .u5cd6aef2be4ac77d9250387a2ad3286e:active , .u5cd6aef2be4ac77d9250387a2ad3286e:hover { opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #2C3E50; } .u5cd6aef2be4ac77d9250387a2ad3286e .centered-text-area { width: 100%; position: relative ; } .u5cd6aef2be4ac77d9250387a2ad3286e .ctaText { border-bottom: 0 solid #fff; color: #2980B9; font-size: 16px; font-weight: bold; margin: 0; padding: 0; text-decoration: underline; } .u5cd6aef2be4ac77d9250387a2ad3286e .postTitle { color: #FFFFFF; font-size: 16px; font-weight: 600; margin: 0; padding: 0; width: 100%; } .u5cd6aef2be4ac77d9250387a2ad3286e .ctaButton { background-color: #7F8C8D!important; color: #2980B9; border: none; border-radius: 3px; box-shadow: none; font-size: 14px; font-weight: bold; line-height: 26px; moz-border-radius: 3px; text-align: center; text-decoration: none; text-shadow: none; width: 80px; min-height: 80px; background: url(https://artscolumbia.org/wp-content/plugins/intelly-related-posts/assets/images/simple-arrow.png)no-repeat; position: absolute; right: 0; top: 0; } .u5cd6aef2be4ac77d9250387a2ad3286e:hover .ctaButton { background-color: #34495E!important; } .u5cd6aef2be4ac77d9250387a2ad3286e .centered-text { display: table; height: 80px; padding-left : 18px; top: 0; } .u5cd6aef2be4ac77d9250387a2ad3286e .u5cd6aef2be4ac77d9250387a2ad3286e-content { display: table-cell; margin: 0; padding: 0; padding-right: 108px; position: relative; vertical-align: middle; width: 100%; } .u5cd6aef2be4ac77d9250387a2ad3286e:after { content: ""; display: block; clear: both; } READ: Oedipus Trilogy EssayDELINQUENCYDave in his teen years was for the most part a very well behaved boy. He wasworking hard in school and kept to himself for the most part. Although Dave did have asmall problem he like to take things with out asking or stealing. Daves stealing habitsstem from his basic survival needs that he instinctively put up when his mother wouldmake him go with out food, water, and basic sanitation. Dave at times would also lashout at his foster families so that they would not get to close to him. In some cases whenDave would lash out he would be put into another foster home and have to readjust tothings again. Dave usually liked to lash out he thought h e didnt need anyone just himself. He could handle himself since he could handle his mother Games and Tests. Davesdelinquent actions are fairly normal of abused and neglected teens. Dave was also justbeing a normal teen trying find himself in a world that had not found him for almost 12years. DEPRESSIONDave did have a great deal of depression in his life. He would think why does mymother treat me like I am a piece of *censored*? Daves depression stemmed from he long oursof being with himself. He had many hours, day, months, and years to think about what hehad done. His mother made him out to be an evil unwanted child who was worthless. Dave thought the main reason his mother didnt like him and his father wouldnt talk tohim any more that he had failed as a son. Not till Dave was in foster care and his fosterparents brought him to a therapist did Dave realize what had happened to him was to hisfault and Dave was a normal boy. His mother was suffering from alcoholism and manicdepression and her outlasted were targeted at him cause he was his fathers pride and joy. His father ignored him to please his wife (Daves mother). His father also started drinkingto drowned his sorrows. SUICIDEYou would think that since Dave was so brutally abused and his own motherstabbed him almost to death with out even drinking him to the hospital he would havewanted even once to kill himself. I know that if anyone did anything like Daves motherdid to me and I had to change homes 7 different times and had kids picking on me cause Ismelled or I didnt have a real mom or dad I would want to kill myself. Not Dave, he onlyworked harder to live and please anyone including his mother so that in hopes she wouldstop this unlawful actions against him. Not once did Dave even want to end his lifeinstead of thinking negatively he would say When I get older and out of here, I will be abetter man I will be the man my father once was. Dave during his time at his mothershouse always held his dad on a pedestal. No mater what happened Daves dad wasSuperman to him. Dave would think of f lying away with his dad to a better place wherehe would be a person not just a Child called It (Peltzers first book). Dave also vowedthat if her were to kill himself that he would only be surrendering to him mothers wishesand even though he tired to please his mother that is the one thing he would not let herhave was his well deserved life. ANOREXIA-BULIMIA NERVOSAThe way Daves mother treated him is shocking. There was one way that Davesmother had complete control over him and that was what he could and couldnt eat. Mostof the time Dave was not permitted to eat. When Dave went to school he would stealother kids lunches so that he could eat food that was not spoiled. Dave did get in troublefor this sever times. After the third time Daves mother made him run home faster than allthe other children and vomit in to the toilet to see if he had stolen. Daves mother wouldsome make him eat rotten pork and chicken one every 3 weeks that is the only food hewould get and if Dave purged he would have another Game and Test to do for hismother. Dave had become so good at hiding what he had ate that he would vomit beforehe left school so that he could at least enjoy his home or at least what home he had. Daveat times would try to steal food that his brothers didnt eat but if he was caught he wouldhave to go in the tub of ice water or d eal with the pneumonia and bleach combination inthe bathroom with no ventilation. When Dave made is way out of his mother house intofoster care. Dave would try to salvage food so that if by chance the foster family wouldnot let him eat he would be able to have food. If Dave was caught with the food he hadtaken and his foster family went to talk to him he would go to the bathroom and vomit sothat he would please them. .u6c1e23433a289c08d50e3dc801d368eb , .u6c1e23433a289c08d50e3dc801d368eb .postImageUrl , .u6c1e23433a289c08d50e3dc801d368eb .centered-text-area { min-height: 80px; position: relative; } .u6c1e23433a289c08d50e3dc801d368eb , .u6c1e23433a289c08d50e3dc801d368eb:hover , .u6c1e23433a289c08d50e3dc801d368eb:visited , .u6c1e23433a289c08d50e3dc801d368eb:active { border:0!important; } .u6c1e23433a289c08d50e3dc801d368eb .clearfix:after { content: ""; display: table; clear: both; } .u6c1e23433a289c08d50e3dc801d368eb { display: block; transition: background-color 250ms; webkit-transition: background-color 250ms; width: 100%; opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #95A5A6; } .u6c1e23433a289c08d50e3dc801d368eb:active , .u6c1e23433a289c08d50e3dc801d368eb:hover { opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #2C3E50; } .u6c1e23433a289c08d50e3dc801d368eb .centered-text-area { width: 100%; position: relative ; } .u6c1e23433a289c08d50e3dc801d368eb .ctaText { border-bottom: 0 solid #fff; color: #2980B9; font-size: 16px; font-weight: bold; margin: 0; padding: 0; text-decoration: underline; } .u6c1e23433a289c08d50e3dc801d368eb .postTitle { color: #FFFFFF; font-size: 16px; font-weight: 600; margin: 0; padding: 0; width: 100%; } .u6c1e23433a289c08d50e3dc801d368eb .ctaButton { background-color: #7F8C8D!important; color: #2980B9; border: none; border-radius: 3px; box-shadow: none; font-size: 14px; font-weight: bold; line-height: 26px; moz-border-radius: 3px; text-align: center; text-decoration: none; text-shadow: none; width: 80px; min-height: 80px; background: url(https://artscolumbia.org/wp-content/plugins/intelly-related-posts/assets/images/simple-arrow.png)no-repeat; position: absolute; right: 0; top: 0; } .u6c1e23433a289c08d50e3dc801d368eb:hover .ctaButton { background-color: #34495E!important; } .u6c1e23433a289c08d50e3dc801d368eb .centered-text { display: table; height: 80px; padding-left : 18px; top: 0; } .u6c1e23433a289c08d50e3dc801d368eb .u6c1e23433a289c08d50e3dc801d368eb-content { display: table-cell; margin: 0; padding: 0; padding-right: 108px; position: relative; vertical-align: middle; width: 100%; } .u6c1e23433a289c08d50e3dc801d368eb:after { content: ""; display: block; clear: both; } READ: Women In Combat (426 words) EssayI feel Dave Peltzer has been through an unimaginable childhood and adolescentlife. I think the book is a heart felt story of a boys struggle for acceptance and aiming toplease those around him. I feel if anyone can over come what Dave has over come thatwhat he tells is accurate in the most scary way possible. Scary in a sense that anyonecould handle such hard ships and still be alive to tell about it. Dave was stabbed,poisoned, neglected, beaten, uprooted from him home at age 15, bounced from fosterhome to foster home without having a real place to call home. I think that this book addressed the real things that happen to a child of abuse. Forthere initial home life to the bounce from foster care home to home. The real issue in thebook that child abuse is everywhere in every degree. Some are hidden ways such asverbal and some are so extreme that a child has no where to turn but to the abuse itself. This book more than anyone could imagine my anticipations and expectationswere met 120%. The book was very descriptive and helpful on how to deal with teens incrisis. I would recommend this book and Dave Peltzers other two books. The main reason isthat the book describes Daves journey to find acceptance and a place to call home really touchedmy soul. The tears I cry for all the kids out there that need a voice to be heard. Mrs. Gold is Godsend She was Daves social worker she took the time to understand Daves story and be his voicefor him. We need more people in the Human Services field like the ones who have helped Davein his journey. This book is a good book for people who work in any type of Human Service jobsuch as a YMCA or a foster family just to show at what lengths kids will go to be safe and saved. Psychology Essays